Effect of preparation conditions on nanostructural features of the NAFION® type perfluorinated proton conducting membranes

Authors:
Yu. V. Kul’velis, V. T. Lebedev, V. A. Trunov, O. N. Primachenko, S. Ya. Khaikin, D. Torok, S. S. Ivanchev
The year of the publication:
2012
Journal:
Petroleum Chemistry N 8 vol. 52 565 - 570
Keywords:
perfluorinated membranes, small-angle neutron scattering, structure, water content, proton conductivity
Abstract:

Features of the fine structure of three samples of perfluorinated Nafion® type membranes—Nafion-115, its Russian analogue MF-4SK, and a new similar material PFM-E produced according to our novel water-emulsion technique—have been characterized using the small-angle neutron scattering technique. A difference in the regularity of common elements of fine structure (cylindrical channels) in the membranes has been revealed. Nafion-115 has the most regular structure with a diffraction peak corresponding to the double channel diameter and an additional broad maximum in the scattering curve indicating a long-range order in the arrangement of straight cylindrical channels. For MF-4SK, in addition, twisted and less ordered channels have been observed. In the PFM-E sample channels have a tortuous and branched structure with diameters similar to Nafion-115. Only a short-range order (40–50 Å) in the arrangement of the channels has been detected, and correlation in their mutual orientation at longer distances is weakened. It has been supposed that the observed branched structure of the channels promotes an increase in water content and an improvement in proton conductivity.

Scroll To Top